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Bromine azide : ウィキペディア英語版
Bromine azide

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Bromine azide is an explosive inorganic compound with the formula BrN3. It has been described as a crystal or a red liquid at room temperature. It is extremely sensitive to small variations in temperature and pressure, thus extreme caution must be observed when working with this reagent. This property of bromine azide has led to difficulty in discerning its crystal structure, with explosions occurring at Δp ≥ 0.05 Torr and also upon crystallization. Despite this, a crystal structure of bromine azide has been obtained using a miniature zone-melting procedure with focused infrared laser radiation. In contrast to IN3, which forms an endless chain-like structure upon crystallization, BrN3 forms a helical structure.
==Preparation==
Bromine azide may be prepared by the reaction of sodium azide with Br2. This reaction forms bromine azide and sodium bromide:〔
:NaN3 + Br2 → BrN3 + NaBr

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